Provided that your C implementation offers a way to ensure that the layout of your structure is the same as the layout that the driver in question uses for writing the buffer, a pretty good way to go about this would be to have the driver write directly into the structure. I'm inferring the signature of the driver function here, but that would probably be something like:
UART2_readTimeout(uartR2, (uint8_t *) &values, 54, NULL, 500);
Assuming that uint8_t is an alias for unsigned char or maybe char, it is valid to write into the representation of the structure via a pointer of type uint8_t *. Thus, this avoids you having to make a copy.
The trick, however, is the structure layout. Supposing that you expect the data to be laid out as the structure members given, in the order given, with no gaps, such a structure layout would prevent structure instances being positioned in memory so that all members are aligned on addresses that are multiples of their sizes. Depending on the alignment rules of your hardware, this might be perfectly fine, but probably either it would slow accesses to some of the members, or it would make attempts to access some of the members crash the program.
if you still want to proceed then you will need to check your compiler's documentation for information about how to get the wanted layout of your structure. You might look for references to structure "packing", structure layout, or structure member alignment. There is no standard way to do this -- if your C implementation supports it at all then that constitutes an extension, with implementation-specific details.
All the same issues and caveats would apply to using memcpy to copy the buffer contents onto an instance of your structure type, so if you don't multiple copies of the data and you can arrange to make bulk copy onto the structure work, then you're better off writing directly onto the structure than writing into a separate buffer and then copying.
On the other hand, the safe and standard alternative would be to allow your implementation to lay out the structure however it thinks is best, And to copy the data out of your buffer into the structure in member-by-member fashion, with per-member memcpy()s. Yes, the code will be a bit tedious, but it will not be sensitive to alignment-related issues, nor even to reordering structure members or adding new ones.