Suppose you take an RV32 program and try running it on a 64-bit system, what compatibility issues are likely to arise?
As I understand it, the instruction encoding is the same, and on RISC-V (like other modern RISC architectures, though unlike x86), ALU operations automatically operate on whatever the word size is, so if you add the contents of a pair of registers, you will get a 32-bit or 64-bit addition as applicable. Load and store of course work on an explicitly specified size because they depend on how many bytes have been allocated in memory.
One theoretically possible compatibility issue would arise if the code depends on bits past 32 being discarded, e.g. add 2^31 to itself and compare the result with zero.
Another more practical issue would arise if the operating system supplies memory addresses outside the first 4 gigabytes, which would be garbled when the code stores the addresses in 32-bit variables.
Are there any other issues I am missing?