It works because you're using the "comma operator", which evaluates the subexpressions on the left and right, and has the value from the right-hand expression.
So in (1,2,3,4,5), 1 is evaluated and the result is discarded, then 2,3,4,5... in which (because of the next comma) 2 is evaluated and the result discarded, then 3,4,5... in which 3 is evaluated and discarded, then 4,5... in which 4 is evaluated and discarded, then 5 which becomes the result of the expression.
As for when it's useful, mainly as a shortcut when you need to evaluate several (sub)expressions for their side effects but aren't interested in their values (except maybe the last one). It's sometimes convenient in for loop expressions, such as when incrementing two variables:
for (i=0,j=1; j < len; i++,j++) {
..where it appears in both the initialization expression and the loop expression.